2.0?Journal of Analytical Procedures in ChemistryBTB Wavelengths max (nm) 414 pH three.0 two.0?4 Beer’s law limits (g mL-1 ) Molar absorptivity 2.1787 three.9244 1.8904 2.4457 0.9386 3.3572 1.9365 four.1976 1.2876 1.4126 1.198 (L/mol-1 cm-1 ) ?104 Sandell’s sensitivity 22.3 12.four 25.7 19.9 51.7 13.0 22.six ten.four 34.0 25.4 30.0 (ng cm-2 ) log five.25 ?0.13 four.90 ?0.ten 4.95 ?0.08 five.36 ?0.12 four.76 ?0.09 4.86 ?0.07 four.98 ?0.11 5.12 ?0.09 five.20 ?0.07 4.82 ?0.12 5.14 ?0.09 Regression equationa Intercept () 0.0016 0.0042 0.0087 0.0064 -0.0006 -0.0091 -0.0058 -0.0137 0.0299 0.0066 0.0005 Slope () 0.0447 0.0805 0.0382 0.0498 0.0196 0.0764 0.0441 0.0953 -0.0023 0.0393 0.0334 Correlation coefficient () 0.9998 0.9999 0.9993 0.9997 0.9996 0.9991 0.9997 0.9994 0.9995 0.9998 0.9995 0.23 0.26 0.52 0.28 0.87 0.21 0.56 0.25 0.41 0.48 0.51 LOD (g mL-1 )b 0.77 0.87 1.73 0.93 2.90 0.70 1.87 0.83 1.37 1.60 1.70 LOQ (g mL-1 )b Imply ?SD 99.80 ?1.14 99.60 ?0.74 99.90 ?0.90 99.75 ?1.05 99.65 ?0.86 99.95 ?0.74 one hundred.ten ?1.07 99.60 ?0.82 99.70 ?0.79 100.05 ?0.98 99.80 ?0.87 RSD 1.14 0.74 0.90 1.05 0.86 0.74 1.07 0.82 0.79 0.98 0.87 RE 1.20 0.77 0.94 1.ten 0.90 0.78 1.12 0.86 0.83 1.03 0.91 -testc 0.23 0.50 0.19 0.29 0.42 0.01 0.11 0.26 0.19 0.24 0.07 -testc three.49 1.47 2.18 two.96 1.98 1.35 1.54 1.ten 1.19 1.24 1.ParametersBCG 420 3.0 1.0?ab= + , exactly where is the concentration in g mL-1 and will be the absorbance units. LOD: limit of detection; LOQ: limit of quantification; : molar absorptivity. c The theoretical values of and at = 0.05 are 2.571 and five.05, respectively.Table 2: Intraday and interday precision and accuracy data for GMF obtained by the proposed procedures.MethodAdded (g mL-1 )BCGBCPBPBBTBMO5.0 ten 15 4.0 8.0 12 five.0 ten 15 five.0 ten 15 ten 20Recovery 99.30 99.50 99.10 100.60 99.20 100.20 one hundred.10 99.80 99.70 99.60 one hundred.10 100.40 99.60 99.80 100.30 Recovery 100.60 99.30 99.90 99.30 99.70 one hundred.30 99.60 99.40 100.20 99.70 99.30 100.20 99.50 99.70 100.Intraday Precision RSD a Accuracy RE 0.53 -0.80 0.Fmoc-1-Nal-OH Order 65 -0.132182-92-4 site 50 0.PMID:23398362 82 -0.90 0.47 0.60 0.72 -0.80 1.17 0.20 0.49 0.ten 0.79 -0.20 1.01 -0.30 0.65 -0.40 0.88 0.10 0.93 0.40 0.44 -0.40 0.68 -0.20 0.98 0.30 Confidence limitb four.996 ?0.026 9.950 ?0.065 14.865 ?0.122 four.024 ?0.019 7.936 ?0.057 12.024 ?0.141 five.005 ?0.025 9.98 ?0.079 14.955 ?0.151 four.98 ?0.032 ten.01 ?0.088 15.06 ?0.140 9.96 ?0.044 19.96 ?0.136 30.09 ?0.Interday Precision RSD a Accuracy RE 0.43 0.60 0.59 -0.70 0.83 -0.ten 0.51 -0.70 0.70 -0.30 1.10 0.30 0.62 -0.40 0.87 -0.60 1.24 0.20 0.54 -0.30 0.75 -0.70 1.08 0.20 0.52 -0.50 0.83 -0.30 1.20 0.Confidence limitb 5.03 ?0.022 9.930 ?0.059 14.985 ?0.124 three.988 ?0.02 7.976 ?0.056 12.036 ?0.132 four.98 ?0.031 9.94 ?0.086 15.03 ?0.23 four.985 ?0.027 9.93 ?0.074 15.03 ?0.162 9.95 ?0.052 19.94 ?0.166 30.06 ?0.aJournal of Analytical Techniques in ChemistrybMean of six determinations; RSD : percentage relative normal deviation; RE : percentage relative error. Self-confidence limit at 95 self-assurance level and five degrees of freedom ( = two.571).Journal of Analytical Approaches in ChemistryTable three: Intraday and interday precision and accuracy information for MXF obtained by the proposed strategies.MethodAdded (g mL-1 )BCPBPBBTBMO2.0 six.0 10 five.0 ten 15 two.0 six.0 ten five.0 10Recovery 99.50 one hundred.20 one hundred.50 99.20 99.50 99.70 99.40 99.20 99.50 100.30 100.60 99.90 Recovery 99.00 99.60 99.80 one hundred.30 99.20 99.60 one hundred.ten 99.70 99.30 100.40 99.80 99.Intraday Precision RSD a Accuracy RE 0.36 -0.50 0.57 0.20 0.81 0.50 0.42 -0.80 0.76 -0.50 0.90 -0.30 0.50 -0.60 0.79 -0.80 1.05 -0.50 0.42 0.30 0.